Table of Contents

August 2008
Volume 108, Issue 8
Pages 2793-3442

About the Cover: Mankind has always cherished metals, especially those found within group 11 of the modern Periodic Table, oftentimes appearing in the form of currency. In contrast to their current symbols, some of those used by alchemists throughout the centuries (as prominently held in chiral arrays) were quite artistic, albeit by design cryptic in nature. What could be the origins of these particular symbols for Cu, Ag, and Au? For further reference, see http://www.rsc.org/chemsoc/visualelements//pages/alchemist/alchemy.html.See the Introduction by Lipshutz and Yamamoto, p. 2793.

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Coinage Metals in Organic Synthesis
Bruce Lipshutz and Yoshinori Yamamoto, Guest Editors

Introduction: Coinage Metals in Organic Synthesis

Bruce H. Lipshutz and Yoshinori Yamamoto
pp 2793–2795
Publication Date (Web): August 13, 2008 (Review)
DOI: 10.1021/cr800415x
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Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions

A. Alexakis, J. E. Bäckvall, N. Krause, O. Pàmies and M. Diéguez
pp 2796–2823
Publication Date (Web): August 1, 2008 (Review)
DOI: 10.1021/cr0683515
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Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents

Syuzanna R. Harutyunyan, Tim den Hartog, Koen Geurts, Adriaan J. Minnaard and Ben L. Feringa
pp 2824–2852
Publication Date (Web): August 13, 2008 (Review)
DOI: 10.1021/cr068424k
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Asymmetric Synthesis of Tertiary Alcohols and α-Tertiary Amines via Cu-Catalyzed C−C Bond Formation to Ketones and Ketimines

Masakatsu Shibasaki and Motomu Kanai
pp 2853–2873
Publication Date (Web): June 21, 2008 (Review)
DOI: 10.1021/cr078340r
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Copper-Catalyzed Asymmetric Alkylation of Imines with Dialkylzinc and Related Reactions

Ken-ichi Yamada and Kiyoshi Tomioka
pp 2874–2886
Publication Date (Web): July 25, 2008 (Review)
DOI: 10.1021/cr078370u
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Enantioselective Copper-Catalyzed 1,3-Dipolar Cycloadditions

Levi M. Stanley and Mukund P. Sibi
pp 2887–2902
Publication Date (Web): July 10, 2008 (Review)
DOI: 10.1021/cr078371m
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Catalytic Asymmetric Friedel−Crafts Alkylation ReactionsCopper Showed the Way

Thomas B. Poulsen and Karl Anker Jørgensen
pp 2903–2915
Publication Date (Web): May 24, 2008 (Review)
DOI: 10.1021/cr078372e
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CuH-Catalyzed Reactions

Carl Deutsch and Norbert KrauseBruce H. Lipshutz
pp 2916–2927
Publication Date (Web): July 11, 2008 (Review)
DOI: 10.1021/cr0684321
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Directed Reactions of Organocopper Reagents

Bernhard Breit and Yvonne Schmidt
pp 2928–2951
Publication Date (Web): June 14, 2008 (Review)
DOI: 10.1021/cr078352c
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Cu-Catalyzed Azide−Alkyne Cycloaddition

Morten Meldal and Christian Wenzel Tornøe
pp 2952–3015
Publication Date (Web): August 13, 2008 (Review)
DOI: 10.1021/cr0783479
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Selective Multiaddition of Organocopper Reagents to Fullerenes

Yutaka Matsuo and Eiichi Nakamura
pp 3016–3028
Publication Date (Web): July 25, 2008 (Review)
DOI: 10.1021/cr0684218
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Organocuprates and Diamagnetic Copper Complexes: Structures and NMR Spectroscopic Structure Elucidation in Solution

Ruth M. Gschwind
pp 3029–3053
Publication Date (Web): August 13, 2008 (Review)
DOI: 10.1021/cr800286r
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Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis

Gwilherm Evano, Nicolas Blanchard and Mathieu Toumi
pp 3054–3131
Publication Date (Web): August 13, 2008 (Review)
DOI: 10.1021/cr8002505
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Asymmetric Silver-Catalyzed Reactions

Marina Naodovic and Hisashi Yamamoto
pp 3132–3148
Publication Date (Web): July 19, 2008 (Review)
DOI: 10.1021/cr068413r
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Ag-Mediated Reactions: Coupling and Heterocyclization Reactions

Jean-Marc Weibel, Aurélien Blanc and Patrick Pale
pp 3149–3173
Publication Date (Web): July 11, 2008 (Review)
DOI: 10.1021/cr078365q
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Silver-Mediated Synthesis of Heterocycles

Míriam Álvarez-Corral, Manuel Muñoz-Dorado and Ignacio Rodríguez-García
pp 3174–3198
Publication Date (Web): July 17, 2008 (Review)
DOI: 10.1021/cr078361l
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Silver-Catalyzed Csp−H and Csp−Si Bond Transformations and Related Processes

Yoshihiko Yamamoto
pp 3199–3222
Publication Date (Web): July 9, 2008 (Review)
DOI: 10.1021/cr078359u
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Carbonyl and Olefin Adducts of Coinage Metals Supported by Poly(pyrazolyl)borate and Poly(pyrazolyl)alkane Ligands and Silver Mediated Atom Transfer Reactions

H. V. Rasika Dias and Carl J. Lovely
pp 3223–3238
Publication Date (Web): August 13, 2008 (Review)
DOI: 10.1021/cr078362d
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Gold-Catalyzed Organic Transformations

Zigang Li, Chad Brouwer and Chuan He
pp 3239–3265
Publication Date (Web): July 10, 2008 (Review)
DOI: 10.1021/cr068434l
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Alternative Synthetic Methods through New Developments in Catalysis by Gold

Antonio Arcadi
pp 3266–3325
Publication Date (Web): July 24, 2008 (Review)
DOI: 10.1021/cr068435d
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Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective

Eloísa Jiménez-Núñez and Antonio M. Echavarren
pp 3326–3350
Publication Date (Web): July 18, 2008 (Review)
DOI: 10.1021/cr0684319
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Ligand Effects in Homogeneous Au Catalysis

David J. Gorin, Benjamin D. Sherry and F. Dean Toste
pp 3351–3378
Publication Date (Web): July 25, 2008 (Review)
DOI: 10.1021/cr068430g
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Coinage Metal Catalyzed C−H Bond Functionalization of Hydrocarbons

M. Mar Díaz-Requejo and Pedro J. Pérez
pp 3379–3394
Publication Date (Web): August 13, 2008 (Review)
DOI: 10.1021/cr078364y
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Coinage Metal-Assisted Synthesis of Heterocycles

Nitin T. Patil and Yoshinori Yamamoto
pp 3395–3442
Publication Date (Web): July 9, 2008 (Review)
DOI: 10.1021/cr050041j
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